A Concise Introduction to Ceramics by George Phillips

By George Phillips

To Cera1l1ics by way of George C. Phillips V AN NOSTRAND REINHOLD ____ manhattan Copyright ('> 1991 by means of Van Nostrand Reinhold Softcover reprint of the hardcover 1 st variation 1991 Library of COnRreSS Catalog Card quantity 91.19587 ISBN.13: 978.94.011--6975.2 All rights eserve r d. No a part of this paintings coated via the copyright hereon could be rcproduccd or uscd in any shape or by means of any means-graphic. digital. or meehaniclli. together with photocopying. recording. taping. or details garage and retrieval systems-without written permission of the writer. synthetic within the u . s . a . released by way of Van Nostrand Reinhold one hundred fifteen 5th road manhattan. big apple 10003 Chapman and Ha ll 2-6 Boundary Row London. SEI SHN. England Thomas Nelson Australia 102 Dodds highway South Melbourne 3205 Victoria. Australia Nelson Canada 1120 Birchmounl highway Scarborough. Ontario M IK 5G4. Canada sixteen 15 14 thirteen 12 II 10 nine eight 7 6 five four three 2 Library or Congress Cataloging-in. ebook information Phillips. George C .. 1937- A concise inlrodu!;tion to ceramics/by George C. Phillips. p. cm. contains bibliographical referen!;es and index. ISBN-13: 978-94-011--6975-2 e-ISBN-13: 978-94-011--6973-8 001:10: 1007/978-94-011--6973-8 I. Cerami!;s. L Tille.

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UPPER PUNCH L----LOWER PUNCH FIGURE 4-3. Compaction occurs under punch pressure. -_ PART FIGURE 4-4. After the pressing operation, the formed part is ejected. CHAMBER- FIGURE 4-5. Forming in a pressure chamber. These problems are alleviated by agglomerating the finer particles into larger granulars in the range of 100 to 150 microns. The resulting microstructure from this agglomeration is shown in Figure 4-6. The voids, which are the limiting features of the surfaces, between the agglomerates are in the range of 15 to 20 microns, which is considerably larger than the one micron grain size of the starting powder.

The aluminum alloys require a chromate surface treatment that produces a chrome oxide layer for adhesion. Copper, gold, and silver require only a clean surface for adhesion to the enamel. 7 CEMENTS Cements are hydraulic bonding agents that are mixed with aggregate stone to form concrete. Cements are made by reacting clay and limestone together at high temperatures. The resulting powders are dicalcium and tricalcium silicates, which when mixed with water form a siliceous bond. When water is added to cement, it initiates an irreversible process; part of the water forms a permanent bond, and the excess water is used to form a slurry that can be poured into a form.

5 THERMAL TREATMENTS Drying is necessary to remove the excess water from parts made by plastic forming or slip casting. The different types of water in a c1aywater system include: 1. 2. 3. 4. 5. Suspension water from slip casting. Interparticle water from plastic forming. Pore water between particles after shrinking. Physically and chemically adsorbed water on the particles. Lattice water within the crystal structure. The different stages of drying are represented in Figure 4-12. The initial removal of the suspension and interparticle water results in shrinkage, as shown in the figure.

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