Graffiti in the PAC Ten by Marina N. Haan

By Marina N. Haan

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Rev. Environ. Contam. T o x i c o l , i n press). However, as pointed out e a r l i e r , w i t h l i p o p h i l i c solutes t h i s e f f e c t w i l l be confounded w i t h the e f f e c t of surfactants on the p a r t i t i o n c o e f f i c i e n t . Both e f f e c t s act i n opposite d i r e c t i o n . The p a r t i t i o n i n g e f f e c t w i l l decrease permeability, whereas an increase i n m o b i l i t y of solutes i n the c u t i c l e w i l l increase the permeability. I n an experiment comparing the uptake of a p e s t i c i d e w i t h and without a surfactant (or a formulation) the two e f f e c t s could cancel and i t would be concluded that the surfactant had no e f f e c t on the c u t i c l e .

The discrete area was marked by using waterproof drawing ink. A l l applications were made using a Burkard Microapplicator PAX 100 f i t t e d with a 50 u l syringe and PFTE coated needle. Each treatment was replicated three times i n a randomized complete block design. At indicated times the treated leaf was removed and washed with 5 ml water. This procedure removed 100% of the glyphosate immediately a f t e r droplet a p p l i c a t i o n . A 1-ml aliquot from the wash was added to 10 ml hydroluma (Lumac/3 M)• Radioactivity was quantified using standard l i q u i d s c i n t i l l a t i o n spectrometry techniques.

Doct. Diss. ;Riederer, M. Plant Cell Environ. 1986, 9, 459 Becher, P. I n P e s t i c i d e Formulations; Valkenburg W. ; Dekker: New York, 1973; p 65 G r i f f i n , W. C. J. Soc. ;Lendzian, K. Z. Pflanzenphysiol. ; Schönherr, J. E c o t o x i c o l . Environ. Safety 1985, 9, 196 Haas K,; Schönherr J. Planta 1976, 146, 399 P a r r , J. ; Norman, A. G. Bot. Gaz. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1988. Chapter 4 Studies on Octylphenoxy Surfactants Effects of Concentration and Mixtures on 2-(1-Naphthyl)acetic Acid Sorption by Tomato Fruit Cuticles 1 Warren E.

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