Optoacoustic Spectroscopy and Detection by Yoh-Han Pao

By Yoh-Han Pao

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J. Chem. Phys. 58, 2922. 3 Design of Optoacoustic Systems C. F o r b e s D e w e y , Jr. Department of Mechanical Engineering Massachusetts Institute of Technology Cambridge, Massachusetts I. II. III. IV. I. Introduction Sample Chamber Design A. Calculation of Acoustic Signals B. Sample Chamber Design C. Practical Design Considerations Wavelength and Amplitude Modulation of the Excitation Source A. Methods of Excitation Beam Modulation B. Acoustically Resonant Operation C. Spectrophones with Wavelength-Modulated Optical Sources Comparison with Other Analytic Techniques References 47 49 49 54 57 62 63 64 65 70 76 Introduction T h e o p t o a c o u s t i c effect h a s b e e n e m p l o y e d in a w i d e v a r i e t y of e x p e r i m e n t a l s i t u a t i o n s , e a c h h a v i n g its p a r t i c u l a r n e e d s w i t h r e s p e c t to sensitivity, accuracy, d y n a m i c r a n g e , s a m p l e c o n d i t i o n i n g , a n d m e a s u r e m e n t 47 48 C.

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